Tag Archives: JEE Main Syllabus
Entranceindia announces free JEE Main Sample Papers for registered users at Entranceindia. We bring best of the class JEE Main 2014 Model Papers both in online as well as DVD mode. Our JEE Main Model Papers for 2013 were unbelievable as 9 questions came in the JEE main examination out of our model papers. For JEE Main 2014 we have released many practice papers as follows:
1. JEE Main Achiever’s Plan Online and DVD mode:
This plan offers chapter-wise tests as well as full syllabus model papers for JEE main examination. In each chapter there are fifty questions with detailed solution. There are three levels of tests to prepare students through a gradual method of learning. Our test papers are prepared by experts providing coaching for JEE Main as well as JEE Advanced. Selection and compilation of questions are based on many criteria to have best questions from exam point of view. Both chapter-wise preparation as well as full syllabus preparation makes this package an unique strategy for JEE Main 2014 preparation.
2. JEE Main 2014 Model Papers (15+1 sets):
This package is for those who need to practice only full syllabus model papers without chapter-wise questions. We have prepared 15+1 model papers for JEE Main 2014, each model paper having 90 questions covering the entire JEE Main syllabus. Our model papers are exactly in the JEE Main pattern having 30 questions each from Physics, Chemistry and Mathematics. Each correct response will award 4 marks and each incorrect response will deduct one mark. We have also combined past exam papers online practice free along with this practice options. This plan is available both in online as well as DVD mode.
3. JEE Main 2014 Model Papers (10+1 Sets)
This is another option for JEE main model papers having 10+1 sets both in online as well as DVD mode. Each model paper carries 90 questions with detail solution. Students can see solution only after attempting the model paper test. They can see their score report immediately after the test submission. This test is beneficial for both online as well as offline students appearing JEE main 2014. Past exam papers are available for online practice along with this JEE main package.
4. JEE Main Test Series (Random Tests) DVD:
This is a randomized test out of a database of more than 6000 questions. This test series is available only on DVD mode. Each time you click on the test maker option it will show you 30 questions in each subject out of the database through random pickup. Each question carries 4 marks and for each incorrect response there is provision for minus one mark penalty. You can view the test report immediately after attending the test and can view the solution irrespective your response.
It was the year 2013 when our JEE Main model papers were proved to be the best one in industry by exact matching of 9 questions out of our model papers in the JEE Main examination. Students were very much enthralled by seeing the same question what they practiced in our model papers. Our model papers are prepared by experts engaged in coaching for JEE main and JEE advanced for years. We have both online and DVD versions of model papers catering to the needs of various categories of students. Apart from model question papers in JEE main pattern, we provide chapter wise tests and past exam question papers tests to students to boost their confidence and enable them to face different categories of questions in the examination. We have compiled 3 DVDs for students of JEE main 2014. You can order any one of them as per your choice and requirement:
DVD Option 1; JEE Main Achiever’s Plan DVD (Set of 3 DVDs):
This is a set of 3 DVDs specially designed for students want to prepare in depth for the JEE Main exam. There are chapter wise tests in JEE Main pattern covering the entire JEE Main Syllabus (Class XI and XII). In each chapter there are 3 different levels of test and there are 50 questions per chapter. 15+1 Model papers are given for practice each model paper having 90 questions from the full syllabus. All the chapter tests and model papers come with detail solution and report about your test result.
Same plan is available in online mode also.
DVD Option 2; JEE Main Success Series Model Papers DVD (15+1 Sets):
This DVD is divided into two parts; one is Test Maker and Model Papers. In test maker section there will be randomized tests out of a database of more than 5000 questions. Once you click for a test it will present 30 questions in a particular subject to be attempted. Next time you click the test it will present another random set of questions different from previously presented set in a particular subject. You can take unlimited tests in each subject each time experiencing new questions to make your preparation more meaningful and interesting. The second part covers Model papers and each model paper contains 90 questions from Physics, Chemistry and Mathematics. These model papers can also be attempted for unlimited number of times. All the test series and model papers come with detailed solution and report about your test result.
The JEE Main Model Papers (15+1 Sets) can also be taken in online mode.
DVD Option 3; JEE Main Test Maker DVD (with detailed solution)
In test maker section there will be randomized tests out of a database of more than 5000 questions. Once you click for a test it will present 30 questions in a particular subject to be attempted. Next time you click the test it will present another random set of questions different from previously presented set in a particular subject. You can take unlimited tests in each subject each time experiencing new questions to make your JEE Main preparation more meaningful and interesting. All the test maker questions come with detailed solution and report about your test result.
You can also attempt our free Sample papers online. Click here to login for free JEE Main sample papers
1. Date of Birth
Only those candidates whose date of birth falls on or after October 01, 1990 are eligible. However, in the case of Scheduled Caste (SC), Scheduled Tribe (ST) and Persons with Disabilities (PwD) candidates, upper age limit is relaxed by 5 years, i.e. SC, ST and PwD candidates who are born on or after October 01, 1985 are eligible. Date of birth as recorded in the Secondary Education Board/University certificate will only be considered.
2. Year of Appearance in Qualifying Examination (QE)
Only those candidates who have passed their Class 12th Exam or any equivalent qualifying examination in 2013 or 2014; or those who are appearing in their Class 12th Exam or any equivalent qualifying examination in 2015 are eligible to appear in JEE (Main) – 2015. Candidates who passed Class 12th/Qualifying examination in 2012 or before as well as those who will appear in such examination in 2016 or later are not eligible to appear in JEE (Main)-2015. Candidates who appeared in class 12th/equivalent qualifying Examinations in 2012, did not pass in 2011, but passed in 2012 are also not eligible to appear in JEE (Main) 2014.
3. Number of subjects in the Qualifying Examination (QE)
Candidates must have taken at least five subjects in class 12th/ qualifying examination in order to be eligible for writing JEE (Main) – 2014. The candidates who have taken four subjects are not permitted to write JEE (Main) 2014 and if such candidates appear in JEE (Main) 2014 by furnishing wrong information, their rank/result will not be declared.
4. Number of Attempts
The number of attempts which a candidate can avail at JEE (Main) shall be limited to 03 (three).
Candidates are also advised to note and verify for themselves the eligibility for appearing in JEE (ADVANCED) – 2015 as well as eligibility for admission to various institutes. Being eligible to write JEE (Main) and by obtaining an ALL INDIA RANK in JEE (Main), A candidate does not automatically become eligible for admission.
5. Score and Result for JEE (Main) – 2015
I. The score of Paper-I of JEE (Main) – 2015 for all candidates will be declared by 3rd May 2015. This score shall comprise the actual marks obtained in Paper-I of JEE (Main) – 2015 along with the status of those who qualify for appearing in JEE (Advanced) – 2015 provided and subject to other conditions of eligibility being met.
II. Separately, on the basis of score in JEE (Main)-2014 and normalised score in Class 12th or equivalent qualifying exam (60% & 40% weightage respectively), separate rank lists will be prepared for December 18, 2015 . Admission to B.E./B. Tech. and B. Arch/ B. Planning (in institutions other than IITs). This will be declared by 7th of July 2015. JEE (Main) -2015 Rank Card indicating All India Rank, State Rank and Category Rank with total marks and marks in each paper will be available on JEE (Main) website after the declaration of result.
III. Only the All India Rank (AIR) is used for admissions through Central Counselling Board to NITs/IIITs/CFTIs/SFIs/Others, while other ranks are for information purposes.
IV. It has been decided that, from this year, no score/rank card will be dispatched to the candidates and the candidates are advised to download their score/rank cards from the JEE (Main) website http://jeemain.nic.in only.
V. In case of a tie, i.e. when two or more candidates obtain equal marks (by giving 60% weightage to performance in JEE (Main) and 40% weightage to normalised marks in Class 12th or equivalent qualifying examination), inter-se merit of such candidates shall be decided in the following order: Rank list for admission to B.E/B.Tech(in institutions other than IITs)
• Resolution by marks obtained in Mathematics in JEE (Main) – 2015. Candidate obtaining higher marks will be given better rank.
• Resolution by marks obtained in Physics in the JEE (Main) – 2015. Candidate obtaining higher marks will be given better rank.
• Resolution by total normalised qualifying exam marks. Candidate obtaining higher normalised marks will be given better rank.
• Resolution by finding the ratio of positive marks and negative marks. Candidate having higher absolute value of the ratio will be given better rank.
• If the resolution is not possible after this criterion, candidates will be given the same rank.
Rank list for admission to B.Arch/B.Planning(in institutions other than IITs)
• Resolution by marks obtained in Aptitude Test in Paper-2 (B. Arch./B. Planning.) in JEE (Main) – 2015. Candidate obtaining higher marks will be given better rank.
• Resolution by marks obtained in Drawing Test in Paper-2 (B. Arch./B. Planning.) in JEE (Main) – 2015. Candidate obtaining higher marks will be given better rank.
• Resolution by total normalised qualifying exam marks. Candidates obtaining higher normalised marks will be given better rank.
• Resolution by finding the ratio of positive marks and negative marks. Candidate having higher absolute value of the ratio will be given better rank.
• If the resolution is not possible after this criterion, candidates will be given the same rank.
VI. The answer keys and images of response sheets (OMR sheets) of Pen & Paper Based examination and Computer based examination will be displayed on the website www.jeemain.nic.in during 25-27 April 2015. The candidates, who are not satisfied with the captured response, may challenge by filling online application form and paying a sum of Rs.1000/- per question The challenge of answer keys will also be accepted online only through the link available on the website www.jeemain.nic.in up to 5.00 PM on 27/04/2015 on payment of Rs.1000/- per question. The fee can be paid by credit/debit card or e-challan. The fee once paid is non-refundable. The JAB’s/CBSE’s decision on the challenges shall be final and no further communication will be entertained.
VII. All participating institutes that do not use the centralised counselling procedures will prepare their own ranking based on the performance in JEE (Main)-2015 and other criteria as decided by them.
JEE Main 2015 Links:-
UNIT 1: SETS, RELATIONS AND FUNCTIONS:
Sets and their representation; Union, intersection and complement of sets and their algebraic properties; Power set; Relation, Types of relations, equivalence relations, functions;. one-one, into and onto functions, composition of functions.
UNIT 2: COMPLEX NUMBERS AND QUADRATIC EQUATIONS:
Complex numbers as ordered pairs of reals, Representation of complex numbers in the form a+ib and their representation in a plane, Argand diagram, algebra of complex numbers, modulus and argument (or amplitude) of a complex number, square root of a complex number, triangle inequality, Quadratic equations in real and complex number system and their solutions. Relation between roots and co-efficients, nature of roots, formation of quadratic equations with given roots.
UNIT 3: MATRICES AND DETERMINANTS:
Matrices, algebra of matrices, types of matrices, determinants and matrices of order two and three.
Properties of determinants, evaluation of determinants, area of triangles using determinants. Adjoint and evaluation of inverse of a square matrix using determinants and elementary transformations, Test of consistency and solution of simultaneous linear equations in two or three variables using determinants and matrices.
UNIT 4: PERMUTATIONS AND COMBINATIONS:
Fundamental principle of counting, permutation as an arrangement and combination as selection, Meaning of P (n,r) and C (n,r), simple applications.
UNIT 5: MATHEMATICAL INDUCTION:
Principle of Mathematical Induction and its simple applications.
UNIT 6: BINOMIAL THEOREM AND ITS SIMPLE APPLICATIONS
Binomial theorem for a positive integral index, general term and middle term, properties of Binomial coefficients and simple applications.
UNIT 7: SEQUENCES AND SERIES:
Arithmetic and Geometric progressions, insertion of arithmetic, geometric means between two given numbers. Relation between A.M. and G.M. Sum upto n terms of special series: S n, S n2, Sn3.
Arithmetico – Geometric progression.
UNIT 8: LIMIT, CONTINUITY AND DIFFERENTIABILITY:
Real – valued functions, algebra of functions, polynomials, rational, trigonometric, logarithmic and exponential functions, inverse functions. Graphs of simple functions. Limits, continuity and differentiability. Differentiation of the sum, difference, product and quotient of two functions. Differentiation of trigonometric, inverse trigonometric, logarithmic, exponential, composite and implicit functions; derivatives of order upto two. Rolle’s and Lagrange’s Mean Value Theorems. Applications of derivatives: Rate of change of quantities, monotonic – increasing and decreasing functions, Maxima and minima of functions of one variable, tangents and normals.
UNIT 9: INTEGRAL CALCULUS:
Integral as an anti – derivative. Fundamental integrals involving algebraic, trigonometric, exponential and logarithmic functions. Integration by substitution, by parts and by partial fractions. Integration using trigonometric identities.
Evaluation of simple integrals of the type Integral as limit of a sum. Fundamental Theorem of Calculus. Properties of definite integrals. Evaluation of definite integrals, determining areas of the regions bounded by simple curves in standard form.
UNIT 10: DIFFERENTIAL EQUATIONS:
Ordinary differential equations, their order and degree. Formation of differential equations. Solution of differential equations by the method of separation of variables, solution of homogeneous and linear differential equations of the type:
dy+ p (x) y = q (x)
UNIT 11: CO-ORDINATE GEOMETRY:
Cartesian system of rectangular co-ordinates 10 in a plane, distance formula, section formula, locus and its equation, translation of axes, slope of a line, parallel and perpendicular lines, intercepts of a line on the coordinate axes.
Various forms of equations of a line, intersection of lines, angles betweentwo lines, conditions for concurrence of three lines, distance of a point from a line, equations of internal and external bisectors of angles between two lines, coordinates of centroid, orthocentre and circumcentre of a triangle, equation of family of lines passing through the point of intersection of two lines.
Circles, conic sections
Standard form of equation of a circle, general form of the equation of a circle, its radius and centre, equation of a circle when the end points of a diameter are given, points of intersection of a line and a circle with the centre at the origin and condition for a line to be tangent to a circle, equation of the tangent. Sections of cones, equations of conic sections (parabola, ellipse and hyperbola) in standard forms, condition for y = mx + c to be a tangent and point (s) of tangency.
UNIT 12 THREE DIMENSIONAL GEOMETRY:
Coordinates of a point in space, distance between two points, section formula, direction ratios and direction cosines, angle between two intersecting lines.
Skew lines, the shortest distance between them and its equation. Equations of a line and a plane in different forms, intersection of a line and a plane, coplanar lines.
UNIT 13: VECTOR ALGEBRA:
Vectors and scalars, addition of vectors, components of a vector in two dimensions and three dimensional space, scalar and vector products, scalar and vector triple product.
UNIT 14: STATISTICS AND PROBABILITY:
Measures of Dispersion: Calculation of mean, median, mode of grouped and ungrouped data calculation of standard deviation, variance and mean deviation for grouped and ungrouped data.
Probability: Probability of an event, addition and multiplication theorems of probability, Baye’s theorem, probability distribution of a random variate, Bernoulli trials and Binomial distribution.
UNIT 15: TRIGONOMETRY:
Trigonometrical identities and equations. Trigonometrical functions. Inverse trigonometrical functions and their properties. Heights and Distances.
UNIT 16: MATHEMATICAL REASONING:
Statements, logical operations and, or, implies, implied by, if and only if. Understanding of tautology, contradiction, converse and contrapositive
UNIT 1: SOME BASIC CONCEPTS IN CHEMISTRY
Matter and its nature, Dalton’s atomic theory; Concept of atom, molecule, element and compound; Physical quantities and their measurements in Chemistry, precision and accuracy, significant figures, S.I. Units, dimensional analysis; Laws of chemical combination; Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae; Chemical equations and stoichiometry.
UNIT 2: STATES OF MATTER
Classification of matter into solid, liquid and gaseous states.
Gaseous State: Measurable properties of gases; Gas laws – Boyle’s law, Charle’s law, Graham’s law of diffusion, Avogadro’s law, Dalton’s law of partial pressure; Concept of Absolute scale of temperature; Ideal gas equation; Kinetic theory of gases (only postulates); Concept of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour, compressibility factor and van der Waals equation.
Properties of liquids – vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only).
Classification of solids: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea); Bragg’s Law and its applications; Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, imperfection in solids; Electrical, magnetic and dielectric properties.
UNIT 3: ATOMIC STRUCTURE
Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric effect; Spectrum of hydrogen atom, Bohr model of hydrogen atom – its postulates, derivation of the relations for energy of the electron and radii of the different orbits, limitations of Bohr’s model; Dual nature of matter, de-Broglie’s relationship, Heisenberg uncertainty principle. Elementary ideas of quantum mechanics, quantum mechanical model of atom, its important features, ?? and ??2, concept of atomic orbitals as one electron wave functions; Variation of ?? and ??2 with r for 1s and 2s orbitals; various quantum numbers (principal, angular momentum and magnetic quantum numbers) and their significance; shapes of s, p and d – orbitals, electron spin and spin quantum number; Rules for filling electrons in orbitals – aufbau principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration of elements, extra stability of half-filled and completely filled orbitals.
UNIT 4: CHEMICAL BONDING AND MOLECULAR STRUCTURE
Kossel – Lewis approach to chemical bond formation, concept of ionic and covalent bonds.
Ionic Bonding: Formation of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy.
Covalent Bonding: Concept of electronegativity, Fajan’s rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules.
Quantum mechanical approach to covalent bonding:Valencebond theory – Its important features, concept of hybridization involving s, p and d orbitals;
Molecular Orbital Theory – Its important features, LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi-bonds, molecular orbital electronic configurations of homonuclear diatomic molecules, concept of bond order, bond length and bond energy.
Elementary idea of metallic bonding. Hydrogen bonding and its applications.
UNIT 5: CHEMICAL THERMODYNAMICS
Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.
First law of thermodynamics – Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess’s law of constant heat summation;
Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization and solution.
Second law of thermodynamics; Spontaneity of processes; DS of the universe and DG of the system as criteria for spontaneity, Dgo (Standard Gibbs energy change) and equilibrium constant.
UNIT 6: SOLUTIONS
Different methods for expressing concentration of solution – molality, molarity, mole fraction, percentage (by volume and mass both), vapour pressure of solutions and Raoult’s Law – Ideal and non-ideal solutions, vapour pressure – composition, plots for ideal and non-ideal solutions; Colligative properties of dilute solutions – relative lowering of vapour pressure, depression of freezing point, elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance.
UNIT 7: EQUILIBRIUM
Meaning of equilibrium, concept of dynamic equilibrium.
Equilibria involving physical processes: Solid -liquid, liquid – gas and solid – gas
equilibria, Henry’s law, general characterics of equilibrium involving physical processes.
Equilibria involving chemical processes: Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance, significance of DG and DGo in chemical equilibria, factors affecting equilibrium concentration, pressure, temperature, effect of catalyst; Le Chatelier’s principle.
Ionic equilibrium: Weak and strong electrolytes, ionization of electrolytes, various concepts of acids and bases (Arrhenius, Br??nsted – Lowry and Lewis) and their ionization, acid – base equilibria (including multistage ionization) and ionization constants, ionization of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, solubility of sparingly soluble salts and solubility products, buffer solutions.
UNIT 8: REDOX REACTIONS AND ELECTROCHEMISTRY
Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing of redox reactions.
Eectrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities and their variation with concentration:
Kohlrausch’s law and its applications.
Electrochemical cells – Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode potential, half – cell and cell reactions, emf of a Galvanic cell and its measurement; Nernst equation and its applications; Relationship between cell potential and Gibbs’ energy change; Dry cell and lead accumulator; Fuel cells.
UNIT 9 : CHEMICAL KINETICS
Rate of a chemical reaction, factors affecting the rate of reactions: concentration, temperature, pressure and catalyst; elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential and integral forms of zero and first order reactions, their characteristics and half – lives, effect of temperature on rate of reactions –
Arrhenius theory, activation energy and its calculation, collision theory of bimolecular gaseous reactions (no derivation).
UNIT-10 : SURFACE CHEMISTRY
Adsorption- Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases on solids – Freundlich and Langmuir adsorption isotherms, adsorption from solutions.
Colloidal state – distinction among true solutions, colloids and suspensions, classification of colloids – lyophilic, lyophobic; multi molecular, macromolecular and associated colloids (micelles), preparation and properties of colloids -
Tyndall effect, Brownian movement, electrophoresis, dialysis, coagulation and flocculation; Emulsions and their characteristics.
SECTION – B
UNIT 11: CLASSIFICATON OF ELEMENTS AND PERIODICITY IN PROPERTIES
Modem periodic law and present form of the periodic table, s, p, d and f block elements, periodic trends in properties of elements atomic and ionic radii, ionization enthalpy, electron gain enthalpy, valence, oxidation states and chemical reactivity.
UNIT 12: GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF METALS
Modes of occurrence of elements in nature, minerals, ores; Steps involved in the extraction of metals – concentration, reduction (chemical and electrolytic methods) and refining with special reference to the extraction of Al, Cu, Zn and Fe; Thermodynamic and electrochemical principles involved in the extraction of metals.
UNIT 13: HYDROGEN
Position of hydrogen in periodic table, isotopes, preparation, properties and uses of hydrogen; Physical and chemical properties of water and heavy water; Structure, preparation, reactions and uses of hydrogen peroxide; Hydrogen as a fuel.
UNIT 14: S – BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)
Group – 1 and 2 Elements
General introduction, electronic configuration and general trends in physical and chemical properties of elements, anomalous properties of the first element of each group, diagonal relationships.
Preparation and properties of some important compounds – sodium carbonate and sodium hydroxide; Industrial uses of lime, limestone, Plaster of Paris and cement; Biological significance of Na, K, Mg and Ca.
UNIT 15: P – BLOCK ELEMENTS
Group – 13 to Group 18 Elements
General Introduction: Electronic configuration and general trends in physical and chemical properties of elements across the periods and down the groups; unique behaviour of the first element in each group.
Groupwise study of the p – block elements
Group – 13
Preparation, properties and uses of boron and aluminium; properties of boric acid, diborane, boron trifluoride, aluminium chloride and alums.
Group – 14
Allotropes of carbon, tendency for catenation; Structure & properties of silicates, and zeolites.
Group – 15
Properties and uses of nitrogen and phosphorus; Allotrophic forms of phosphorus; Preparation, properties, structure and uses of ammonia, nitric acid, phosphine and phosphorus halides, (PCl3, PCl5); Structures of oxides and oxoacids of phosphorus.
Group – 16
Preparation, properties, structures and uses of ozone; Allotropic forms of sulphur; Preparation, properties, structures and uses of sulphuric acid (including its industrial preparation); Structures of oxoacids of sulphur.
Group – 17
Preparation, properties and uses of hydrochloric acid; Trends in the acidic nature of hydrogen halides; Structures of Interhalogen compounds and oxides and oxoacids of halogens.
Occurrence and uses of noble gases; Structures of fluorides and oxides of xenon.
UNIT 16: d – and f – BLOCK ELEMENTS
General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first row transition elements – physical properties, ionization enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties, complex formation, interstitial compounds, alloy formation; Preparation, properties and uses of K2 Cr2 O7 and KMnO4.
Inner Transition Elements
Lanthanoids – Electronic configuration, oxidation states and lanthanoid contraction.
Actinoids – Electronic configuration and oxidation states.
UNIT 17: CO-ORDINATION COMPOUNDS
Introduction to co-ordination compounds, Werner’s theory; ligands, coordination number, denticity, chelation; IUPAC nomenclature of mononuclear co-ordination compounds, isomerism; Bonding-Valence bond approach and basic ideas of Crystal field theory, colour and magnetic properties; Importance of co-ordination compounds (in qualitative analysis, extraction of metals and in biological systems).
UNIT 18: ENVIRONMENTAL CHEMISTRY
Environmental pollution – Atmospheric, water and soil.
Atmospheric pollution – Tropospheric and Stratospheric
Tropospheric pollutants – Gaseous pollutants: Oxides of carbon, nitrogen and sulphur, hydrocarbons; their sources, harmful effects and prevention; Green house effect and Global warming; Acid rain;
Particulate pollutants: Smoke, dust, smog, fumes, mist; their sources, harmful effects and prevention.
Stratospheric pollution- Formation and breakdown of ozone, depletion of ozone layer – its mechanism and effects.
Water Pollution – Major pollutants such as, pathogens, organic wastes and chemical pollutants; their harmful effects and prevention.
Soil pollution – Major pollutants such as: Pesticides (insecticides,. herbicides and fungicides), their harmful effects and prevention.
Strategies to control environmental pollution.
UNIT 19: PURIFICATION AND CHARACTERISATION OF ORGANIC COMPOUNDS
Purification – Crystallization, sublimation, distillation, differential extraction and chromatography – principles and their applications.
Qualitative analysis – Detection of nitrogen, sulphur, phosphorus and halogens.
Quantitative analysis (basic principles only) – Estimation of carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus.
Calculations of empirical formulae and molecular formulae; Numerical problems in organic quantitative analysis.
UNIT 20: SOME BASIC PRINCIPLES OF ORGANIC CHEMISTRY
Tetravalency of carbon; Shapes of simple molecules – hybridization (s and p);
Classification of organic compounds based on functional groups: – C = C – , – Ch C – and those containing halogens, oxygen, nitrogen and sulphur;
Homologous series; Isomerism – structural and stereoisomerism.
Nomenclature (Trivial and IUPAC)
Covalent bond fission – Homolytic and heterolytic: free radicals, carbocations and carbanions; stability of carbocations and free radicals, electrophiles and nucleophiles.
Electronic displacement in a covalent bond
- Inductive effect, electromeric effect, resonance and hyperconjugation.
UNIT 21: HYDROCARBONS
Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties and reactions.
Alkanes – Conformations: Sawhorse and Newman projections (of ethane);
Mechanism of halogenation of alkanes.
Alkenes – Geometrical isomerism; Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoff’s and peroxide effect); Ozonolysis and polymerization.
Alkynes – Acidic character; Addition of hydrogen, halogens, water and hydrogen halides; Polymerization.
Aromatic hydrocarbons – Nomenclature, benzene – structure and aromaticity;
Mechanism of electrophilic substitution: halogenation, nitration, Friedel – Craft’s alkylation and acylation, directive influence of functional group in monosubstituted benzene.
UNIT 22: ORGANIC COMPOUNDS CONTAINING HALOGENS
General methods of preparation, properties and reactions; Nature of C-X bond;
Mechanisms of substitution reactions.
Uses; Environmental effects of chloroform & iodoform.
UNIT 23: ORGANIC COMPOUNDS CONTAINING OXYGEN
General methods of preparation, properties, reactions and uses.
ALCOHOLS, PHENOLS AND ETHERS
Alcohols: Identification of primary, secondary and tertiary alcohols; mechanism of dehydration.
Phenols: Acidic nature, electrophilic substitution reactions: halogenation, nitration and sulphonation, Reimer – Tiemann reaction.
Aldehyde and Ketones: Nature of carbonyl group;Nucleophilic addition to >C=O group, relative reactivities of aldehydes and ketones; Important reactions such as – Nucleophilic addition reactions (addition of HCN, NH3 and its derivatives),
Grignard reagent; oxidation; reduction (Wolff Kishner and Clemmensen); acidity of ı – hydrogen, aldol condensation, Cannizzaro reaction, Haloform reaction; Chemical tests to distinguish between aldehydes and Ketones.
Acidic strength and factors affecting it.
UNIT 24: ORGANIC COMPOUNDS CONTAINING NITROGEN
General methods of preparation, properties, reactions and uses.
Amines: Nomenclature, classification, structure, basic character and identification of primary, secondary and tertiary amines and their basic character.
Diazonium Salts: Importance in synthetic organic chemistry.
UNIT 25: POLYMERS
General introduction and classification of polymers, general methods of polymerization-addition and condensation, copolymerization;
Natural and synthetic rubber and vulcanization; some important polymers with emphasis on their monomers and uses – polythene, nylon, polyester and bakelite.
UNIT 26: BIOMOLECULES
General introduction and importance of biomolecules.
CARBOHYDRATES – Classification: aldoses and ketoses; monosaccharides (glucose and fructose) and constituent monosaccharides of oligosacchorides (sucrose, lactose and maltose).
PROTEINS – Elementary Idea of ı – amino acids, peptide bond, polypeptides;
Proteins: primary, secondary, tertiary and quaternary structure (qualitative idea only), denaturation of proteins, enzymes.
VITAMINS – Classification and functions.
NUCLEIC ACIDS – Chemical constitution of DNA and RNA.
Biological functions of nucleic acids.
UNIT 27: CHEMISTRY IN EVERYDAY LIFE
Chemicals in medicines – Analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamins – their meaning and common examples.
Chemicals in food – Preservatives, artificial sweetening agents – common examples.
Cleansing agents – Soaps and detergents, cleansing action.
UNIT 28: PRINCIPLES RELATED TO PRACTICAL CHEMISTRY
• Detection of extra elements (N,S, halogens) in organic compounds; Detection of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl and amino groups in organic compounds.
• Chemistry involved in the preparation of the following:
Inorganic compounds: Mohr’s salt, potash alum.
Organic compounds: Acetanilide, pnitroacetanilide, aniline yellow, iodoform.
• Chemistry involved in the titrimetric excercises – Acids bases and the use of indicators, oxalic-acid vs KMnO4, Mohr’s salt vs KMnO4.
• Chemical principles involved in the qualitative salt analysis:
Cations – Pb2+ , Cu2+, AI3+, Fe3+, Zn2+, Ni2+, Ca2+, Ba2+, Mg2+, NH4+.
Anions- CO3 2-, S2-, SO4 2-, NO2-, NO3-, CI -, Br, I.
(Insoluble salts excluded).
• Chemical principles involved in the following experiments:
1. Enthalpy of solution of CuSO4
2. Enthalpy of neutralization of strong acid and strong base.
3. Preparation of lyophilic and lyophobic sols.
4. Kinetic study of reaction of iodide ion with hydrogen peroxide at room temperature.
The syllabus contains two Sections – A and B. Section – A pertains to the Theory Part having 80% weightage, while Section – B contains Practical Component (Experimental Skills) having 20% weightage.
SECTION – A
UNIT 1: PHYSICS AND MEASUREMENT
Physics, technology and society, S I units, Fundamental and derived units. Least count, accuracy and precision of measuring instruments, Errors in measurement, Dimensions of Physical quantities, dimensional analysis and its applications.
UNIT 2: KINEMATICS
Frame of reference. Motion in a straight line: Position-time graph, speed and velocity. Uniform and non-uniform motion, average speed and instantaneous velocity Uniformly accelerated motion, velocity-time, position-time graphs, relations for uniformly accelerated motion. Scalars and Vectors, Vector addition and Subtraction, Zero Vector, Scalar and Vector products, Unit Vector, Resolution of a Vector. Relative Velocity, Motion in a plane, Projectile Motion, Uniform Circular Motion.
UNIT 3: LAWS OF MOTION
Force and Inertia, Newton’s First Law of motion; Momentum, Newton’s Second Law of motion; Impulse; Newton’s Third Law of motion. Law of conservation of linear momentum and its applications, Equilibrium of concurrent forces.
Static and Kinetic friction, laws of friction, rolling friction.
Dynamics of uniform circular motion: Centripetal force and its applications.
UNIT 4: WORK, ENERGY AND POWER
Work done by a constant force and a variable force; kinetic and potential energies, workenergy theorem, power.
Potential energy of a spring, conservation of mechanical energy, conservative and non-conservative forces; Elastic and inelastic collisions in one and two dimensions.
UNIT 5: ROTATIONAL MOTION
Centre of mass of a two-particle system, Centre of mass of a rigid body; Basic concepts of rotational motion; moment of a force, torque, angular momentum, conservation of angular momentum and its applications; moment of inertia, radius of gyration. Values of moments of inertia for simple geometrical objects, parallel and perpendicular axes theorems and their applications. Rigid body rotation, equations of rotational motion.
UNIT 6: GRAVITATION
The universal law of gravitation. Acceleration due to gravity and its variation with altitude and depth. Kepler’s laws of planetary motion. Gravitational potential energy; gravitational potential. Escape velocity. Orbital velocity of a satellite. Geo-stationary satellites.
UNIT 7: PROPERTIES OF SOLIDS AND LIQUIDS
Elastic behaviour, Stress-strain relationship, Hooke’s Law, Young’s modulus, bulk modulus, modulus of rigidity. Pressure due to a fluid column; Pascal’s law and its applications.
Viscosity, Stokes’ law, terminal velocity, streamline and turbulent flow, Reynolds number. Bernoulli’s principle and its applications. Surface energy and surface tension, angle of contact, application of surface tension – drops, bubbles and capillary rise. Heat, temperature, thermal expansion; specific heat capacity, calorimetry; change of state, latent heat. Heat transferconduction, convection and radiation,Newton’s law of cooling.
UNIT 8: THERMODYNAMICS
Thermal equilibrium, zeroth law of thermodynamics, concept of temperature.
Heat, work and internal energy. First law of thermodynamics. Second law of thermodynamics: reversible and irreversible processes. Carnot engine and its efficiency.
UNIT 9: KINETIC THEORY OF GASES
Equation of state of a perfect gas, work doneon compressing a gas.Kinetic theory of gases – assumptions, concept of pressure. Kinetic energy and temperature: rms speed of gas molecules; Degrees of freedom, Law of equipartition of energy,applications to specific heat capacities of gases; Mean free path, Avogadro’s number.
UNIT 10: OSCILLATIONS AND WAVES
Periodic motion – period, frequency, displacement as a function of time. Periodic functions. Simple harmonic motion (S.H.M.) and its equation; phase; oscillations of a spring -restoring force and force constant; energy in S.H.M. – kinetic and potential energies; Simple pendulum – derivation of expression for its time period; Free, forced and damped oscillations, resonance.
Wave motion. Longitudinal and transverse waves, speed of a wave. Displacement relation for a progressive wave. Principle of superposition of waves, reflection of waves, Standing waves in strings and organ pipes, fundamental mode and harmonics, Beats, Doppler effect in sound
UNIT 11: ELECTROSTATICS
Electric charges: Conservation of charge, Coulomb’s law-forces between two point charges, forces between multiple charges; superposition principle and continuous charge distribution.
Electric field: Electric field due to a point charge, Electric field lines, Electric dipole, Electric field due to a dipole, Torque on a dipole in a uniform electric field.
Electric flux, Gauss’s law and its applications to find field due to infinitely long uniformly charged straight wire, uniformly charged infinite plane sheet and uniformly charged thin spherical shell. Electric potential and its calculation for a point charge, electric dipole and system of charges; Equipotential surfaces, Electrical potential energy of a system of two point charges in an electrostatic field.
Conductors and insulators, Dielectrics and electric polarization, capacitor, combination of capacitors in series and in parallel, capacitance of a parallel plate capacitor with and without dielectric medium between the plates, Energy stored in a capacitor.
UNIT 12: CURRRENT ELECTRICITY
Electric current, Drift velocity, Ohm’s law, Electrical resistance, Resistances of different materials, V-I characteristics of Ohmic and nonohmic conductors, Electrical energy and power, Electrical resistivity, Colour code for resistors; Series and parallel combinations of resistors; Temperature dependence of resistance.
Electric Cell and its Internal resistance, potential difference and emf of a cell, combination of cells in series and in parallel. Kirchhoff’s laws and their applications. Wheatstone bridge, Metre bridge. Potentiometer – principle and its applications.
UNIT 13: MAGNETIC EFFECTS OF CURRENT AND MAGNETISM
Biot – Savart law and its application to current carrying circular loop. Ampere’s law and its applications to infinitely long current carrying straight wire and solenoid. Force on a moving charge in uniform magnetic and electric fields. Cyclotron.
Force on a current-carrying conductor in a uniform magnetic field. Force between two parallel current-carrying conductors-definition of ampere. Torque experienced by a current loop in uniform magnetic field; Moving coil galvanometer, its current sensitivity and conversion to ammeter and voltmeter.
Current loop as a magnetic dipole and its magnetic dipole moment. Bar magnet as an equivalent solenoid, magnetic field lines; Earth’s magnetic field and magnetic elements.Para-, dia- and ferro- magnetic substances.
Magnetic susceptibility and permeability, Hysteresis, Electromagnets and permanent magnets.
UNIT 14: ELECTROMAGNETIC INDUCTION AND ALTERNATING CURRENTS
Electromagnetic induction; Faraday’s law, induced emf and current; Lenz’s Law, Eddy currents. Self and mutual inductance. Alternating currents, peak and rms value of alternating current/ voltage; reactance and impedance; LCR series circuit, resonance; Quality factor, power in AC circuits, wattless current. AC generator and transformer.
UNIT 15: ELECTROMAGNETIC WAVES
Electromagnetic waves and their characteristics. Transverse nature of electromagnetic waves. Electromagnetic spectrum (radio waves, microwaves, infrared, visible, ultraviolet, Xrays, gamma rays). Applications of e.m. waves.
UNIT 16: OPTICS
Reflection and refraction of light at plane and spherical surfaces, mirror formula, Total internal reflection and its applications, Deviation and Dispersion of light by a prism, Lens Formula, Magnification, Power of a Lens, Combination of thin lenses in contact, Microscope and Astronomical Telescope (reflecting and refracting) and their magnifyingpowers.
Wave optics: wavefront and Huygens’ principle, Laws of reflection and refraction using Huygen’s principle. Interference, Young’s double slit experiment and expression for fringe width. Diffraction due to a single slit, width of central maximum. Resolving power of microscopes and astronomical telescopes, Polarisation, plane polarized light; Brewster’s law, uses of plane polarized light and Polaroids.
UNIT 17: DUAL NATURE OF MATTER AND RADIATION
Dual nature of radiation. Photoelectric ef fect , Hertz and Lenard’s observat ions; Einstein’s photoelectric equation; part icle nature of light . Matter waves-wave nature of part icle, de Broglie relation. Davisson-Germer experiment.
UNIT 18: ATOMS AND NUCLEI
Alpha-particle scattering experiment;Rutherford’s model of atom; Bohr model, energy levels, hydrogen spectrum. Composition and size of nucleus, atomic masses, isotopes, isobars; isotones. Radioactivity-alpha, beta and gamma particles/rays and their properties; radioactive decay law. Mass-energy relation, mass defect; binding energy per nucleon and its variation with mass number, nuclear fission and fusion.
UNIT 19: ELECTRONIC DEVICES
Semiconductors; semiconductor diode: I-V characteristics in forward and reverse bias; diode as a rectifier; I-V characteristics of LED, photodiode, solar cell and Zener diode; Zener diode as a voltage regulator. Junction transistor, transistor action, characteristics of a transistor; transistor as an amplifier (common emitter configuration) and oscillator. Logic gates (OR, AND, NOT, NAND and NOR). Transistor as a switch.
UNIT 20: COMMUNICATION SYSTEMS
Propagation of electromagnetic waves in the atmosphere; Sky and space wave propagation, Need for modulation, Amplitude and Frequency Modulation, Bandwidth of signals, Bandwidth of Transmission medium, Basic Elements of a Communication System (Block Diagram only).
UNIT 21: EXPERIMENTAL SKILLS
Familiarity with the basic approach and observations of the experiments and activities:
1. Vernier callipers-its use to measure internal and external diameter and depth of a vessel.
2. Screw gauge-its use to determine thickness/diameter of thin sheet/wire.
3. Simple Pendulum-dissipation of energy by plotting a graph between square of amplitude and time.
4. Metre Scale – mass of a given object by principle of moments.
5. Young’s modulus of elasticity of the material of a metallic wire.
6. Surface tension of water by capillary rise and effect of detergents.
7. Co-efficient of Viscosity of a given viscous liquid by measuring terminal velocity of a given spherical body.
8. Plotting a cooling curve for the relationship between the temperature of a hot body and time.
9. Speed of sound in air at room temperature using a resonance tube.
10. Specific heat capacity of a given (i) solid and (ii) liquid by method of mixtures.
11. Resistivity of the material of a given wire using metre bridge.
12. Resistance of a given wire using Ohm’s law.
13. Potentiometer –
(i) Comparison of emf of two primary cells.
(ii) Determination of internal resistance of a cell.
14. Resistance and figure of merit of a galvanometer by half deflection method.
15. Focal length of:
(i) Convex mirror
(ii) Concave mirror, and
(iii) Convex lens
using parallax method.
16. Plot of angle of deviation vs angle of incidence for a triangular prism.
17. Refractive index of a glass slab using a travelling microscope.
18. Characteristic curves of a p-n junction diode in forward and reverse bias.
19. Characteristic curves of a Zener diode and finding reverse break down voltage.
20. Characteristic curves of a transistor and finding current gain and voltage gain.
21. Identification of Diode, LED, Transistor, IC, Resistor, Capacitor from mixed collection of such items.
22. Using multimeter to:
(i) Identify base of a transistor
(ii) Distinguish between npn and pnp type transistor
(iii) See the unidirectional flow of current in case of a diode and an LED.
(iv) Check the correctness or otherwise of a given electronic component (diode, transistor or IC).
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