JEE Main 2014 Syllabus Chemistry Unit – 21

ORGANIC CHEMISTRY

 Hydrocarbons

Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties and reactions.

Alkanes – Conformations: Sawhorse and Newman projections (of ethane);

Mechanism of halogenation of alkanes.

Alkenes – Geometrical isomerism; Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoff’s and peroxide effect); Ozonolysis and polymerization.

Alkynes – Acidic character; Addition of hydrogen, halogens, water and hydrogen halides; Polymerization.

Aromatic hydrocarbons – Nomenclature, benzene – structure and aromaticity;

Mechanism of electrophilic substitution: halogenation, nitration, Friedel – Craft’s alkylation and acylation, directive influence of functional group in monosubstituted benzene.

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